ask me about being a online and live prop.

[Eponymous]

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Any chance rake/time charge can be itemized as a work related expense deduction against your gross salary?

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It's already included in the wins and losses that anyone who reports their poker wins/losses on their taxes. If they've had a winning session, their winnings are already smaller than what they would have been if the rake wasn't there. If they had a losing session, the loss includes the rake. To list the rake again would be double counting.