Re: 25NL vs 50NL vs 100NL
A lot has already been said. I'd suggest making sure that when you are moving up to NL100 (at least on Stars/Tilt) that you are properly rolled.
Its my experience that a good or even reasonable player can handle things at NL25 or NL50 under rolled, but given the nature of the game above that--you need to be prepared to weather the swings. The situations just continue to get more marginal as you move up and the variance increases because your edges are smaller.
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