[*TT*]

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I have no idea why he would smooth-call QQ on the turn...FPS?

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Because thats what live players do. They are afraid of losing that extra bet, thinking that they would rather raise the river than 5 bet the turn because "then he will know what my hand is". This line from the villain is rather common with QQ or TT.

IMHO its close between calling and 3-balling. In the heat of the battle I call because of the villain's description - this player type usually doesn't spew too much on the river once there has been tons of action. Additionally if he thinks the river just counterfeited your 2-pair he is more likely to just call than raise.