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What about
Modafinil? It is supposed to promote wakefulness and mental alertness without the side effects of speed or caffeine. I've always wanted to try it, but it's being regulated as a controlled substance at this point.
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Excellent choice, Red. What is often not mentioned, and what make this the perfect drug for poker and combat, is that it makes you brave, too.
As a C-4, I wouldn't expect it's DEA classification to change anytime soon. It's also horribly expensive, running around $10 a tablet retail. No idea what that would run on the street.