Somewhere Over the Rainbow - Israel Kamakawiwo'ole Also well known medley with "What a Wonderful World"
Lateralis - Tool Possibly the most inventive time signatures from a rock band throughout this entire album.
Velvet Sky - Los Lonely Boys The entire self-titled album is masterfully recorded, and is music to an audiophile's ears. This is a gem that I don't believe was released as a single.
Note: I don't know what the YouTube links look like because my job blocks access. Best I could do with Google.