[plexiq]

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What I don't understand is why. What is the reason I would get A5s as superior to A6s or, say, AJs against AA if I ran a simulation?

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A5s can make straights with 2 hole cards, and can make more 1-hole card straights than A4s-A2s. A5s and ATs have identical straight potential.

ATs/A5s is better against AA than AJ+s, because they have a higher potential to make straights by using the T/5 only.