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some of my favorites, in no particular order...
Merle, Willie, Alan Jackson, Ricky Van Shelton, Tom T. Hall, George Jones, Ronnie Milsap, Chris LeDuex, Roger Miller, Don Williams, Charlie Rich, Vince Gill, George Strait,
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I can't believe it took this long for someone to mention George Jones.
About.com's all-time top 500 country songs.
Doesn't look a ton like my list would, but there is a lot of good songs/artists on there.